The optical absorption spectrum of cobalt oxide sample was studied by uvvisible spectroscopy. Synthesis of cobalt oxide nanoparticles via homogeneous. Characterization of cobalt oxide co 3 o 4 nanoparticles prepared by various methods. Biosynthesis of nio and ni nanoparticles and their. Table 1 gives the bet surface areas, phases present and the decomposition temperatures used for the thermolysis. Synthesis and characterization of cobalt oxide nanoparticles by thermal treatment process. Designed synthesis of cobaltoxidebased nanomaterials for. Why is 1g of cobalt oxide nanoparticles a better catalyst. Anjali jain deotale under our guidance and supervision for the degree of doctor of philosophy of devi ahilya vishwavidyalaya, indore m. Optical, electrical and structural studies of nickelcobalt. Balela thesis submitted in fulfillment of the requirements for the degree of master of science july 2008. The particle size is determined from xray diffraction studies and tem image. Cobalt is a block d, period 4 element, while oxygen is a block p, period 2 element. Cobalt oxide nanoparticles high purity fast delivery.
The factors that have been studied are the effect of ph, synthesis temperature, capping agent, annealing temperature, and different usage of cobalt salts. Green synthesis of cobalt ii, iii oxide nanoparticles using. Cobalt oxide co3o4 nanoparticles properties, applications. There is evidence that these nanoparticles can cause membrane damage. The cobalt oxide nanoparticles calcined at 450 c were characterized by using xrd. Hydrothermal synthesis of cobalt oxide nanoparticles journal of. Synthesis and characterization of cobaltcontaining.
That the crystalline spherical co 3 o 4 nanoparticles on multiwalled carbon nanotubes are a step towards high. Hydrothermal synthesis of cobalt oxide nanoparticles 343 presence of triton x100 as surfactant, and koh and h2o2 as homogeneous precipitating agents. Synthesis, characterization, and investigation of optical and. Cobalt produces brilliant blue pigments which have been used since ancient times to color paint and glass. The electrochemical detection of nitrobenzene by cobalt oxide nanoparticles was investigated by cyclic voltammetry. Mohammed suleiman abstract in this work, differentsized cobalt oxide nano.
Physiological remediation of cobalt ferrite nanoparticles. Effect of solvents on synthesis and characterization of. Synthesis and characterization of cobalt oxide nanoparticles. Effect of solvents on synthesis and characterization of cobalt oxide co 3 o 4 nanoparticles. Mohammed suleiman abstract one of the major health problems that has been showing up recently, was due to the emergence of new bacterial strains that posses resistant to.
During the nucleation and growth of cobalt sulfide nanoparticles, fnbr acts as a support material and suppress the aggregation of co x s y nanoparticles. Received 22 nd march abstract in the present work, cobalt oxide co 3o4 nanoparticles were synthesized by co of asprepared nanoparticles was confirmed by using x. Electrochemical and electrocatalytic properties of cobalt oxide nanoparticles reza emamali sabzi, fatemeh ebrahimzadeh and hassan sedghi department of chemistry, faculty of science, urmia university, urmia, iran email. Cobalt oxide co 3 o 4 nanoparticles were successfully prepared by thermal decomposition of cobalt hydroxide synthesized from cobalt acetate, ammonium hydroxide and 10% glycerol. Pdf on oct 1, 2017, ismat bibi and others published green synthesis of cobaltoxide nanoparticle. Green synthesis of co3o4 nanoparticles using euphorbia. The xrd confirms the crystallinity and crystal structure of the sample. They are characterized by ftir, xrd, sem and tem techniques.
The co3o4 nanoparticles are spherical shaped with an average size. Cobalt oxide nanoparticlesco3o4npshave many applications and now a. Cobalt oxide co3o4 nanoparticleshave been synthesized by hydrothermal method using mixture of cobaltiichloride, triton x100 and koh in an autoclave at. Cobalt oxidemodified titanium dioxide nanoparticle photocatalyst for degradation of 2,4dichlorophenoxyacetic acid 2,4dichlorophenoxyacetic acid 2,4d has been recognized as a possibly carcinogenic compound to human, therefore, 2,4d should be treated before it. Synthesis and characterization of cobalt nanoparticles using.
Synthesis, characterization, and investigation of optical. Iron oxide and cobalt oxide nanomaterials have been growing excessive importance because of their magnetic characteristics and wide applications. Characterization and photocatalytic activity article pdf available in advanced powder technology 2810 october 2017 with 3,516 reads. The sample of cobalt sulfidefnbr nanocomposite was studied the elemental composition of the phases fig 3b. Chemical engineering department, faculty of engineering, burapha university, 169 longhad bangsean road, t. The dielectric permittivity measurements on the pellets of nickel cobalt oxide nanoparticles were carried out using a home made. Why is 1g of cobalt oxide nanoparticles a better catalyst than 1g of cobalt oxide powder. Cobalt oxide co 3 o 4 nanoparticles, nanodots or nanopowder are black spherical high surface area particles.
Iron oxideand cobalt oxide nanoparticles are prepared by using different methods, precursors, solveemperature conditions. Nanoparticles of nickelcobalt oxide are prepared by chemical coprecipitation method. Recently metaloxide nanoparticles have been the subject of much interest because of their unusual optical, electronic and magnetic properties, which often differ from the bulk. Wet synthesis of monodisperse cobalt oxide nanoparticles. Synthesis, characterization and antibacterial properties of. Cobalt oxide nanoparticle tends to orient itself with its narrow size distribution having a crystal size around 50 nm. This is to certify that the thesis entitled synthesis and characterization of some metal oxide nanoparticles is a piece of research work done by smt. Designed synthesis of cobaltoxidebased nanomaterials for superior electrochemical energy storage devices huajun qiu, li liu, yanping mu, huijuan zhang, and yu wang school of chemistry and chemical engineering, chongqing university, chongqing 400044, china. Pure co 3 o 4 nanoparticles with diameters 3050 nm are fabricated from nn. Moringa oleifera natural extract as high electrochemical. Cobalt oxide nanoparticles were characterized by scanning electron microscopy, energy dispersive x ray spectroscopy, uv, fourier transform infrared. Direct synthesis of co nanoparticles is a possible alternative approach.
Cobalt oxide nanoparticles serve as vital inorganic material with a variety of applications. The results conclude that the cobalt oxide nanoparticles have higher activity for the detection of nitrobenzene. The particles may incorporate other substances, asfor example diphenylalanine cobalt oxide hybrid nanowires. The present investigation reports, the synthesis and characterization of cobalt oxide co 3 o 4 nanoparticles using thermal treatment. Introduction nanotechnology is an intensive branch of science that interesting in the materials among the size of 1100 nm with different shapes of spherical nanoparticles, nanorods, nanoribbons, nanobelts and nanoplatelets 1,2. Synthesis and characterization of cobalt nanoparticles prepared by liquidphase reduction by mary donnabelle l. Green synthesis of cobalt ii, iii oxide nanoparticles using moringa. This study has investigated the different factors in obtaining cobalt oxide nanoparticles. Liquidphase synthesis of cobalt oxide nanoparticles.
Electrochemical and electrocatalytic properties of cobalt. Hydroxyethyl cellulose and cobalt chloride are used as precursor materials for the synthesis of cobalt oxide co 3 o 4 nanoparticles. Short communication chemical synthesis of cobalt oxide co. Synthesis, characterization, and investigation of optical and magnetic properties of cobalt oxide co 3 o 4 nanoparticles. Mohammed suleiman abstract in this work, differentsized cobalt oxide nano rods were selectively. Pdf on oct 1, 2017, ismat bibi and others published green synthesis of cobalt oxide nanoparticle. Sustainable synthesis of cobalt and cobalt oxide nanoparticles and their catalytic and. Nanoparticles strung on nanotubes, like a beaded necklace see figure, have been synthesized by a simple low temperature supercritical solution method. In recent years, synthesis of transition metal oxide nanoparticles has attracted much attention because of their outstanding multifunctional physicalchemical properties for their use in different fields. Synthesis of copper oxide nanoparticles by a novel method.
The particles may incorporate other substances, asfor example diphenylalaninecobalt oxide hybrid nanowires. For the complex figure 1, curve a, the characteristic stretching bands of nh 3, co 3, and no 3 groups are observed at approximately 3,250 to 3,500, 1,600, and 1,350 cm1, respectively. Size dependent antibacterial activity of cobalt oxide. Waghuley department of physics, sant gadge available online at. Synthesis, characterization and antibacterial properties. Cobalt ferrite cofe2o4 is a wellknown hard magnetic material with high coercivity and moderate magnetization. Cobalt oxide nanoparticles have been prepared via homogeneous precipitation using different synthetic conditions. Cobalt oxide nanoparticles induced oxidative stress linked to activation of tnf. The thermal decomposition of the composite is studied using thermogravimetric technique. Controlled continuous hydrothermal synthesis of cobalt. Spineltype cobalt oxide co3o4 nanoparticles have been easily prepared through a simple thermal decomposition route at low temperature. A composite system from polymer and metal chloride is prepared via casting technique. Size dependent antibacterial activity of cobalt oxide nanoparticles by heba awad izzat maloul supervisor dr.
Nanoscale cobalt oxide particles are typically 1030 nanometers nm with specific surface area ssa in the 150 m 2 g range. Cobalt oxide nanoparticles, such as nanotubes, offer high surfacetovolume ratio and short path length for lithium cation transport, leading to high reversible capacity and good cycle life. Various liquidphase syntheses of coo and co3o4 nanoparticles have been studied. Cobalt nanoparticles were produced by employing the liquidphase reduction method and hydrazine. Synthesis and characterization of cobalt nanoparticles. Hydrothermal synthesis of cobalt oxide nanoparticles. The co3o4 nanoparticles are spherical shaped with an average size 26. Cobalt oxide co3o4 nanoparticleshave been synthesized by hydrothermal method using mixture of cobalt iichloride, triton x100 and koh in an autoclave at 180 c for 6 h followed by heating at. When the particle size is reduced below the single domain limit, they show a.
Liquidphase synthesis of cobalt oxide nanoparticles article pdf available in journal of nanoscience and nanotechnology 115. The addition of promoter mainly noble metals has been widely utilized to increase the fraction of cobalt that is available for surface catalysis ref. Synthesis, characterization, and investigation of optical and magnetic properties of cobalt oxide co3o4 nanoparticles article august 20 with 183 reads how we measure reads. Pdf biosynthesis of cobalt oxide nanoparticles a short. After stirring, it was filtered using watman filter paper no. In recent years, transition metal cobalt co and cobalt oxide co3o4. The effect of using cobalt salts with different anions nitrate, acetate, chloride and sulphate and concentrations on the final products has been investigated. Synthesis of nanosized cobalt oxide nanoparticles stabilized in surfactant and polymer matrix and their magnetic properties by fadi mohammad mostafa naalweh supervisor dr. Co3o4 nanoparticles by coprecipitation method and enhanced photocatalytic properties in the visible region article pdf available january 2018. Direct fabrication of cobalt oxide nanoparticles employing. Synthesis of nanosized cobalt oxide nanoparticles stabilized in. The effect of citric acid additives on the formation and growth mechanism of cobalt nanoparticles was investigated using polarization methods. Energy dispersive xray analysis of cobalt sulfide was performed using.
Physiological remediation of cobalt ferrite nanoparticles by. View the article online for updates and enhancements. Chemical synthesis of cobalt oxide synthesis of cobalt oxide isca. Cobalt oxide nanoparticles used in temperature and gas sensors. Characterizations of cobalt oxide nanoparticles within. Further the synthesised ni and nio nanoparticles showed cytotoxic effect against ht29 cell line.
This article discusses the properties and applications of cobalt oxide nanoparticles. Characterization of cobalt oxide co o nanoparticles. Controlled continuous hydrothermal synthesis of cobalt oxide. If inhaled if breathed in, move person into fresh air.
Optical, electrical and structural studies of nickel. Both nio and ni phases were present in the decomposition product of complex c. Certificate this is to certify that the thesis entitled synthesis and characterization of some metal oxide nanoparticles is a piece of research work done by smt. Copper oxide particles such prepared are in nano scale and there morphology and size are characterized using sem, uv visible spectroscopy, ir spectroscopy. Co 3 o 4 shows highcatalytic activity for the oxidation of. Mechanochemical synthesis of cobalt oxide nanoparticles. Characterization and photocatalytic activity find, read and. Cobalt oxide co 3 o 4 nanoparticles of 20 nm size and smaller have a wide interest for many applications including catalysis, sensors, electrochemistry, magnetism, and energy storage. Co 3 o 4 doped with noble metal and rare earth metal oxides are potentially promising catalysts in methane catalytic combustion. Azizib adepartments of physics, faculty of science, university of zabol, zabol, iran bdepartment of physics, faculty of science, university of sistan and baluchestan, zahedan, iran abstract in the current paper,nanostructured nickel oxide nio were. This method is completely a green method, free from toxic and harmful solvent. Pdf liquidphase synthesis of cobalt oxide nanoparticles. Cobalt oxide nanoparticles appear as a white powder with spinel crystal structure.
Cobalt is a ferromagnetic metal and is used primarily in the production of magnetic and highstrength superalloys. Cobalt oxidemodified titanium dioxide nanoparticle. Synthesis of cobalt ferrite nanoparticles via a solgel combustion method 215 in the interval of 20150oc, a 5. These oxide particles mainly exist in the state of co ii o, and can be partly reduced to metallic cobalt with h 2 at temperatures as low as 573 k. Co 3 o 4 doped with noble metal and rare earth metal oxides are potentially promising catalysts in methane catalytic combustion 1. The ftir studies have been used to confirm the formation of metal oxide. Recently, the synthesis of copper oxide and zinc oxide nano particles. Effect of calcination temperatures on size, dimension and catalytic decomposition of hydrogen peroxide s. Show this safety data sheet to the doctor in attendance. Several strategies have been established for the synthesis of cobalt oxide nanoparticles with tunable sizes, morphologies and magnetic properties that involve the use of environmentally malignant. Settakorn upasen, teerawat nongpromma, sirisak trikamol. Magnetic properties of nanoparticles differ significantly from its bulk counterpart.
Synthesis and spectroscopic investigation of cobalt oxide. The absorbance of nio nanoparticles were observed by absorbance spectra and magnetic flux density values are 60 emug of this sample but for metallic nanoparticle of ni there was no absorbance was observed. The effect of sintering on the particle size is analyzed. Synthesis and magnetic properties of cobalt ferrite cofe.
Short communication chemical synthesis of cobalt oxide co k. Synthesis of copper oxide nanoparticles by a novel method and its application 85 for about 20 mins in a magnetic stirrer at room temperature. Combustion method has been used as a fast and facile method to prepare nanocrystalline co 3 o 4 spinel employing glycine as a combustion fuel. Hosseini1 1 chemistry department of imam hussein university, tehran, i. Pdf cobalt oxide co3o4 nanoparticleshave been synthesized by hydrothermal method using mixture of cobaltiichloride, triton x100 and. A major group of organic precursors that have been employed for the synthesis of cobalt and cobalt oxide nanoparticles via a thermal decomposition route is. Pdf hydrothermal synthesis of cobalt oxide nanoparticles. Synthesis of copper oxide nanoparticles by a novel method and. Pellets of nanoparticles of nickel cobalt oxide of diameter mm and thickness 12 mm are made by applying a pressure of 4 tonnes in a hand operated hydraulic press. The ftir spectra of the conh 3 4 co 3no 3 h 2 o complex and its decomposition products at different temperatures are shown in figure 1.
1302 1513 1446 1314 402 675 1144 1010 433 1639 996 1031 46 1178 75 1559 1550 1356 1340 1419 1233 970 1195 836 1430 167 1283 582 947 641 225 13 756 16 201 416 9